2024
DOI: 10.1002/slct.202304976
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Fischer indolization of terpenes and steroids

Sambasivarao Kotha,
Punam Meher

Abstract: Here we report a new synthetic approach to several intricate indoles and hydrazones starting with commercially available terpenes and steroids via Fischer indolization (FI) sequence under deep eutectic solvents (DES) conditions or by employing acetic acid reflux conditions. During the course of the reaction with pulegone 22 and pipertone 25 we observed Fischer indolization along with aromatization is occurring. In another instance, with thujone 32 we found cyclopropane ring is opening under thermal conditions … Show more

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