First Study of thev2= 3 Dyad {(130), (031)} of Ozone through the Analysis of Hot Bands in the 2300–2600 cm−1Region

Extended Analysis of Line Positions and Intensities of Ozone Bands in the 2900–3400 cm−1 Region

“…These parameters give good agreement with the observed line positions for low and medium J and K a values. The maximum discrepancies were 0.2 cm −1 for high values of 3ν 3 (K a = 16−18) and ν 1 + 2ν 3 (K a ≥ 12) bands. The predictions of 2ν 1 + ν 3 and 3ν 1 bands were better: up to 0.085 and 0.050 cm −1 , respectively.…”

“…This set of experimental data covers all transitions of A-and B-type bands. The precision of linestrength measurements was 3-14% (depending on the strength and blending of the lines) for the ν 2 + 2ν 3 , ν 1 + ν 2 + ν 3 , and 2ν 1 + ν 2 bands; 5-18% for the 3ν 3 , ν 1 + 2ν 3 , and 2ν 1 + ν 3 bands; and 10-25% for 3ν 1 band. We have not been able to find any lines of the 4ν 2 and ν 1 + 3ν 2 bands.…”

“…[3], [4]. After assignment, the new lines were fitted using the above rovibrational effective Hamiltonian for a more accurate determination of the parameters of tetrad interacting states {(003), (102), (201), (300)}.…”

“…The analysis of the (130) state from a hot band in the 2400-2600 cm −1 region was performed in Ref. (3). Interactions of the (040) state with the triad {(012), (111), (210)} are discussed in our recent paper (Ref.…”

“…The high-resolution analysis of the 3ν 3 , ν 1 + 2ν 3 , 2ν 1 + ν 3 , and 3ν 1 bands and determination of their band intensities were performed in Refs. (1,2).…”