First principle study of LiXS₂(X= Ga, In) as cathode materials for Li ion batteries

Abstract

From first principle calculations, we demonstrate that LiXS2 (X = Ga, In) compounds have potential applications as cathode materials for Li ion batteries. It is shown that Li can be extracted from the LiXS2 lattice with relatively small volume change and the XS4 tetrahedron structure framework remains stable upon delithiation. The theoretical capacity and average intercalation potential of the LiGaS2 (LiInS2) cathode are 190.4 (144.2) mAh/g and 3.50 V (3.53 V). The electronic structures of the LiXS2 are insulating with band gaps of 2.88 eV and 1.99 eV for X = Ga and In, respectively. However, Li vacancies, which are formed through delithiation, change the electronic structure substantially from insulating to metallic structure, indicating that the electrical conductivities of the LiXS2 compounds should be good during cycling. Li ion migration energy barriers are also calculated, and the results show that Li ion diffusions in the LiXS2 compounds can be as good as those in the currently widely used electrode materials.

Two-dimensional CrP2 with high specific capacity and fast charge rate for lithium-ion battery

“…[16] Recently, many 2D materials have been proposed theoretically as a promising candidate for applications in LIBs. [17][18][19] Multiscale computation methods, including first-principles calcu-lation, molecular dynamics simulation, phase field simulation, finite element, and machine learning, can be applied in discovery and design of new electrode materials. [12] As a relatively new family of monolayer materials, 2D transition metal carbides and nitrides with a general formula of M n+1 X n , namely MXenes, show promising applications as anode materials for LIBs, in view of their excellent electron conduction and high charge/discharge rates.…”