First Nanoparticle-Based EOR Nano-EOR Project in Japan: Laboratory Experiments for a Field Pilot Test

Abstract

"Nanoparticle-based enhanced oil recovery (Nano-EOR)" is an improved waterflooding assisted by nanoparticles dispersed in the injection water. Many laboratory studies have revealed the effectiveness of Nano-EOR. An evaluation of the EOR effect is one of the most critical items to be investigated. However, risk assessments and mitigation plans are as essential as investigation of its effectiveness for field applications. This study examined the items to be concerned for applying Nano-EOR to the Sarukawa oil field, a mature field in Japan, and established an organized laboratory and field tests workflow. This paper discusses a laboratory part of the study in detail. This study investigated the effect and potential risks of the Nano-EOR through laboratory experiments based on the workflow. The laboratory tests used surface-modified nanosilica dispersion, synthetic brine, injection water, and crude oil. The oil and injection water were sampled from a wellhead and injection facility, respectively, to examine the applicability of the EOR at the Sarukawa oil field. The items of the risk assessment involved the influence on an injection well's injectivity, poor oil/water separation at a surface facility, and contamination of sales oil. A series of experiments intended for the Sarukawa oil field showed that 0.5 wt. % nanofluid was expected to contribute to significant oil recovery and cause no damage on an injection well for the reservoir with tens of mD. This is considered a favorable result for applying Nano-EOR to Sarukawa oil field because it contains layers of tens mD. Furthermore, the experiments also showed that 0.5 wt.% nanofluid did not lead to poor oil/water separation and contamination of sales oil. Thus, field tests are designed with this concentration. This paper introduces the entire study workflow and discusses the detailed procedure and results of experiments investigating the Nano-EOR effect and potential risks.

Investigation of Hybrid Nanoparticle–Acid Fluids (HNAFs): Influence of Wettability and Interfacial Tension Mechanisms in Harsh Carbonate Reservoirs for Improved Oil Recovery

“…Afekare et al 22 also showed how aqueous dispersions of hydrophilic nanosilica may have a significant effect on the reduction (>70%) of the rock–oil adhesion force and work of adhesion (>95%), which leads to nanoscale wettability improvement and a potential increase in the recovery factor. Kaito et al 23 utilized a 0.5 wt % surface-modified nanosilica dispersion (SND), which contains 18% colloidal silica nanoparticles and some chemicals to enhance the stability of nanoparticles in synthetic brine, to show that nanoparticles increased oil recovery by 14 points in most core-flooding experiments.…”