Dielectronic recombination has been investigated for ∆n = 1 resonances of ground-state Li + (1s 2 ) and for ∆n = 0 resonances of metastable Li + (1s2s 3 S). The ground-state spectrum shows three prominent transitions between 53 and 64 eV, while the metastable spectrum exhibits many transitions with energies < 3.2 eV. Reasonably good agreement of R-matrix, LS coupling calculations with the measured recombination rate coefficient is obtained. The time dependence of the recombination rate yields a radiative lifetime of 52.2 ± 5.0 s for the 2 3 S level of Li + .PACS number(s): 34.80. Lx, 32.70.Cs, 32.80.Dz In collisions between ions and electrons, recombination [1] can occur either by radiative recombination (RR) (inverse of the photoelectric effect), or by dielectronic recombination (DR). This process starts by the resonant capture of a free electron, mediated by its interaction with a bound electron (inverse of an Auger transition), and then proceeds by a radiative transition to a stable recombined system. Dielectronic recombination is of fundamental interest because it gives insight into electron correlation, and of applied interest for the understanding of astrophysical and laboratory plasmas. Extensive experimental studies providing significant tests of the theory [1] have been conducted for H-like, He-like, and Lilike ions heavier than about carbon. For such systems, perturbative techniques can be successfully used in theoretical calculations because the electron-electron interaction is relatively weak compared to the electron-nucleus interaction. In contrast, for lighter ions perturbative techniques cease to produce results at the same level of accuracy. Hence, high quality data for light systems are required to test the reliability of theoretical predictions.For the lightest H-like ion, He + , DR was studied previously by three groups [2-4] with successively higher energy resolution, and through a consequent feedback between experiment and theory good mutual agreement could be obtained. For the lightest He-like ion, Li + , the two-electron configuration places additional constraints on the theory of RR and DR. Moreover, the existence of relatively long-lived metastable 1s2s 1 S and 1s2s 3 S states with natural lifetimes of about 0.5 ms and 50 s, respectively, requires recombination for both the ground state and the metastable state (especially the long-lived triplet state) to be understood. To date, only lowresolution DR measurements for Li + have been carried out [5]; the integrated ground-state and metastable recombination rates could be extracted, but more detailed comparisons between experiment and theory for specific excited-state configurations were not possible.Here we report a high-resolution investigation of DR in Li + . Individual intermediate-excited state configurations contributing to DR could be resolved for groundstate Li + (1s 2 1 S) ions, where DR occurs via ∆n = 1 resonances (1s 2 + e → 1s2ln ′ l ′ ) at relative electron-ion energies of 53-64 eV, as well as for metastable Li + (1s2s 3 S)...