First application of homogeneous Pd nanoparticles prepared by pulsed laser ablation in liquid to a Suzuki-type reaction

Bonis, Angela De; D’Orsi, Rosarita; Funicello, Maria; Lupattelli, Paolo; Santagata, A.; Teghil, R.; Chiummiento, Lucia

doi:10.1016/j.catcom.2017.06.052

Cited by 10 publications

(8 citation statements)

References 29 publications

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“…Palladium nanoparticles were synthesized by 800 nm, 100 fs pulsed laser ablation of a Pd target in water and by a wet chemistry method as a control material by Chiummiento and co-workers. 363 The Pd nanoparticles were employed as catalysts in a ligand-free Suzuki-type cross-coupling reaction to link methyl-4-bromocrotonate to one of various aryl and heteroarylboronic acids. The authors described a systematic array of conditions and observed that product yields for all products and recyclability were higher for the chemically synthesized Pd catalyst material.…”

Section: Catalysts For Other Organic Reactionsmentioning

confidence: 99%

“…Palladium nanoparticles that were laser-made in water contained higher amounts of surface PdO, which hampered the Suzuki-type catalysis. 363 Nickel−palladium nanoparticles were fabricated by 1064 nm, 7 ns pulsed laser ablation of a nickel plate in aqueous PdCl 2 solution by Choi and co-workers to catalyze 1,2dichlorobenzene dechlorination (Figure 51). 364 The bimetallic composite consisted of ca.…”

Section: Catalysts For Other Organic Reactionsmentioning

confidence: 99%

Section: Thermochemical Heterogeneous Catalysismentioning

confidence: 99%

“…Presumably, chemically made Pd nanoparticles exhibited more edges that benefitted catalysis. Palladium nanoparticles that were laser-made in water contained higher amounts of surface PdO, which hampered the Suzuki-type catalysis …”

Section: Thermochemical Heterogeneous Catalysismentioning

confidence: 99%

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Pulsed Laser in Liquids Made Nanomaterials for Catalysis

et al. 2021

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Catalysis is essential to modern life and has a huge economic impact. The development of new catalysts critically depends on synthetic methods that enable the preparation of tailored nanomaterials. Pulsed laser in liquids synthesis can produce uniform, multicomponent, nonequilibrium nanomaterials with independently and precisely controlled properties, such as size, composition, morphology, defect density, and atomistic structure within the nanoparticle and at its surface. We cover the fundamentals, unique advantages, challenges, and experimental solutions of this powerful technique and review the state-of-the-art of laser-made electrocatalysts for water oxidation, oxygen reduction, hydrogen evolution, nitrogen reduction, carbon dioxide reduction, and organic oxidations, followed by laser-made nanomaterials for light-driven catalytic processes and heterogeneous catalysis of thermochemical processes. We also highlight laser-synthesized nanomaterials for which proposed catalytic applications exist. This review provides a practical guide to how the catalysis community can capitalize on pulsed laser in liquids synthesis to advance catalyst development, by leveraging the synergies of two fields of intensive research.

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Section: Catalysts For Other Organic Reactionsmentioning

confidence: 99%

Section: Catalysts For Other Organic Reactionsmentioning

confidence: 99%

Section: Thermochemical Heterogeneous Catalysismentioning

confidence: 99%

Section: Thermochemical Heterogeneous Catalysismentioning

confidence: 99%

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Pulsed Laser in Liquids Made Nanomaterials for Catalysis

et al. 2021

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“…In the past, homogeneous Pd catalysts made significant progress in Suzuki-Miyaura coupling reactions; however, it is difficult to separate the products and reuse them. To overcome the drawbacks of homogeneous catalysts, heterogeneous catalysts were significantly explored [6][7][8][9][10]. Heterogeneous catalysis has some advantages such as a recyclable catalytic systems, nontoxic ligands, and a lower amount of palladium residues in products [11][12][13][14].…”

Section: Introductionmentioning

confidence: 99%

Novel Magnetically-Recyclable, Nitrogen-Doped Fe3O4@Pd NPs for Suzuki–Miyaura Coupling and Their Application in the Synthesis of Crizotinib

et al. 2018

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Novel magnetically recyclable Fe3O4@Pd nanoparticles (NPs) were favorably synthesized by fixing palladium on the surface of nitrogen-doped magnetic nanocomposites. These catalysts were fully characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), transmission electron microscopy (TEM), thermogravimetric analysis (TG), and X-ray photoelectron spectroscopy (XPS). The prepared catalyst exhibited good catalytic activity for Suzuki–Miyaura coupling reactions of aryl or heteroaryl halides (I, Br, Cl) with arylboronic acids. These as-prepared catalysts could be readily isolated from the reaction liquid by an external magnet and reused at least ten times with excellent yields achieved. In addition, using this protocol, the marketed drug crizotinib (anti-tumor) could be easily synthesized.

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