Energy consumption is associated with economic growth, but it comes with a toll regarding the environment. Renewable energies can be considered substitutes for fossil fuels and may contribute to reducing the environmental degradation that the world is presently facing. With this research, we aimed to offer a broader view of the state-of-the-art in this field, particularly regarding coal and biomass. The main objective is to present a viable and sustainable solution for the coal power plants still in operation, using as a hypothetical example the Pego Power Plant, the last operating coal fueled power plant in Portugal. After the characterization of land use and energy production in Portugal, and more particularly in the Médio Tejo region, where the power plant is located, the availability of biomass was assessed and it was concluded that the volume of biomass needed to keep the Pego power plant working exclusively with biomass is much lower than the yearly growth volume of biomass in the region, which means that this transition would be viable in a sustainable way. This path is aligned with policies to fight climate change, since the use of biomass for energy is characterized by low levels of GHGs emissions when compared to coal. The risk of rural fires would be reduced, and the economic and social impact for this region would be positive.