Fingerprints for Main Varieties of Argentinean Wines: Terroir Differentiation by Inorganic, Organic, and Stable Isotopic Analyses Coupled to Chemometrics

Paola-Naranjo, Romina D. Di; Baroni, María Verónica; Podio, Natalia S.; Rubinstein, H.R.; Fabani, María Paula; Badini, Raúl G.; Inga, Marcela; Ostera, Héctor A.; Cagnoni, Mariana Celina; Gallegos, Ernesto; Gautier, Eduardo A.; Peral‐García, Pilar; Hoogewerff, Jurian; Wunderlin, Daniel Alberto

doi:10.1021/jf2007419

Cited by 151 publications

(124 citation statements)

References 42 publications

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“…The cell gas flow rate was set at 8 mL min -1 and the lens settings were modified to minimize the background at m/z 51 (i.e. 35 Cl 16 O + ) while aspirating a 1% v v -1 HCl solution.…”

Section: Icp-ms Instrumentationmentioning

confidence: 99%

“…Although this technology has been available for more than 10 years, the use of CCT for elemental analysis of wine has been scarce until recently [15][16][17]. The common strategy is based on the use of different sets of conditions for determining spectrally interfered and non-interfered elements, respectively.…”

Section: Introductionmentioning

confidence: 99%

“…Na, Mg, Al, Ca, Ni, Cu, Zn, Sr, Mo, Cd, In, Sn, Ba, Tl and Pb) were measured using the conventional mode. A similar approach was employed by Di Paola-Naranjo et al, [16] but they used a single gas mixture (i.e. He + H 2 ) to access all interfered nuclides.…”

Section: Introductionmentioning

confidence: 99%

“…Finally, it is also worth to mention that contradictory conclusions as to the optimum ICP-MS conditions for the determination of some elements can be found in the literature. For instance, determination of Mn, Ni, Zn, Sr, Mo, Cd, Ba and Pb has been carried out using either conventional ICP-MS [15] or CCT-ICP-MS [16,17].…”

Section: Introductionmentioning

confidence: 99%

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Evaluation of the multi-element capabilities of collision/reaction cell inductively coupled plasma–mass spectrometry in wine analysis

Grindlay¹,

Mora²,

Loos-Vollebregt³

et al. 2014

Talanta

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Evaluation of the multi-element capabilities of collision/reaction cell inductively coupled plasma -mass spectrometry in wine analysis, Talanta, http://dx.doi.org/10.1016/j.talanta. 2014.05.008 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting galley proof before it is published in its final citable form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. AbstractThis work explores the multi-element capabilities of inductively coupled plasma -mass spectrometry with collision/reaction cell technology (CCT-ICP-MS) for the simultaneous determination of both spectrally interfered and non-interfered nuclides in wine samples using a single set of experimental conditions. The influence of the cell gas type (i.e. He, He + H 2 and He + NH 3 ), cell gas flow rate and sample pre-treatment (i.e. water dilution or acid digestion) on the background-equivalent concentration (BEC) of several nuclides covering the mass range from 7 to 238 u has been studied. Results obtained in this work show that, operating the collision/reaction cell with a compromise cell gas flow rate (i.e. 4 mL min -1 ) improves BEC values for interfered nuclides without a significant effect on the BECs for non-interfered nuclides, with the exception of the light elements Li and Be. Among the different cell gas mixtures tested, the use of He or He + H 2 is preferred over He + NH 3 because NH 3 generates new spectral interferences.2 No significant influence of the sample pre-treatment methodology (i.e. dilution or digestion) on the multi-element capabilities of CCT-ICP-MS in the context of simultaneous analysis of interfered and non-interfered nuclides was observed.Nonetheless, sample dilution should be kept at minimum to ensure that light nuclides (e.g. Li and Be) could be quantified in wine. Finally, a direct 5-fold aqueous dilution is recommended for the simultaneous trace and ultra-trace determination of spectrally interfered and non-interfered elements in wine by means of CCT-ICP-MS. The use of the CCT is mandatory for interference-free ultra-trace determination of Ti and Cr. Only Be could not be determined when using the CCT due to a deteriorated limit of detection when compared to conventional ICP-MS.

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“…The cell gas flow rate was set at 8 mL min -1 and the lens settings were modified to minimize the background at m/z 51 (i.e. 35 Cl 16 O + ) while aspirating a 1% v v -1 HCl solution.…”

Section: Icp-ms Instrumentationmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Evaluation of the multi-element capabilities of collision/reaction cell inductively coupled plasma–mass spectrometry in wine analysis

Grindlay¹,

Mora²,

Loos-Vollebregt³

et al. 2014

Talanta

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“…In Argentina, different chemometric procedures have been applied in order to establish quality criteria, genuineness and geographical and varietal differentiation in wine (Fabani, Arrúa, Vázquez, Diaz, Baroni & Wunderlin, 2010;Bentlin, Pulati, Dressler, & Pozebon, 2011;Di Paola-Naranjo et al, 2011;Fanzone et al, 2012), but none of them have applied the spectroscopy methods mentioned above.…”

Section: Introductionmentioning

confidence: 99%

Evaluation of Geographic Origin of Torrontés Wines by Chemometrics

Azcarate¹,

Cantarelli²,

Marchevsky³

et al. 2013

JFR

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This work discusses the determination of the provenance of commercial Torrontés wines from different Argentinean provinces (Mendoza, San Juan, Salta and Rio Negro) by the use of UV-vis spectroscopy and chemometric techniques. In order to find classification models, wines (n = 80) were analyzed using UV-Vis region of the electromagnetic spectrum. Principal component analysis (PCA), linear discriminant analysis (LDA) and partial least squares discriminant analysis (PLS-DA) were used to classify Torrontés wines according to their geographical origin. Classification rates obtained were highly satisfactory. The PLS-DA and LDA calibration models showed that 100% of the Mendoza, San Juan, Salta and Rio Negro Torrontés wine samples had been correctly classified. These results demonstrate the potential use of UV spectroscopy with chemometric data analysis as a method to classify Torrontés wines according to their geographical origin, a procedure which requires low-cost equipment and short-time analysis in comparison with other techniques.

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