Fine Tuning the Hydrophobicity of a New Three-Dimensional Cu2+ MOF through Single Crystal Coordinating Ligand Exchange Transformations
Nikos Panagiotou,
Dimitrios A. Evangelou,
Manolis J. Manos
et al.
Abstract:The synthesis, characterization,
and single–crystal–to–single–crystal
(SCSC) exchange reactions of a new 3D Cu2+ MOF based on
5-aminoisophthalic acid (H2AIP), [Cu6(μ3-ΟΗ)3(ΑΙΡ)4(HΑΙΡ)]
n
·6nDMF·nH2O - UCY-16·6nDMF·nH2O, are reported. It exhibits a 3D structure based on two [Cu4(μ3–OH)2]6+ butterfly–like
secondary building units, differing in their peripheral ligation,
bridged through HAIP–/AIP2– ligands.
This compound displays the capability to exchange the coordinating
ligand(s) and/or guest solvent molecules… Show more
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