“…[ 37 , 39 , 46 ] In addition, more and more recent studies have demonstrated that the regioregular PSMAs could obtain better solid‐state packing, synthetic repeatability, and less energy disorder, eventually leading to enhanced charge transport properties and device performances. [ 17 , 19 , 26 , 34 , 43 , 45 , 46 , 47 , 48 ] Therefore, it is essential to take comprehensive consideration of the DAD cores, end groups, π ‐spacers, and the regiochemistry effect to develop PSMAs toward higher performance.…”