Abstract:Infinities should naturally occur
in the dielectric responses of
ionic solutions relevant to many geochemical, energy storage, and
electrochemical applications at a strictly zero frequency. Using molecular
dynamics simulations cross-referenced with coarse-grained Monte Carlo
models, using nanoslit pore models at hydrothermal conditions, and
treating confined mobile charges as polarization, we demonstrate the
far reaching consequences. The dielectric permittivity profile perpendicular
to the slit (ϵ⊥(z)) increa… Show more
“…27 Consequently, the central questions addressed in this work revolve around how nanoconfinement and surface chemistry modify these interactions and how these altered interactions subsequently influence gas cluster formation. Given that nanoconfinement alters many physicochemical and thermodynamic properties of the confined species compared to their characteristics in a bulk state, [28][29][30][31][32][33][34][35][36] it is reasonable to assume that nanoconfinement significantly enhances or suppresses these interactions, which is ultimately reflected in clustering of gas molecules.…”
Gas molecule clustering within nanopores holds significance in the field of nanofluidic, biology, gas adsorption/desorption, and geological gas storage. However, the intricate roles of nanoconfinement and surface chemistry that govern...
“…27 Consequently, the central questions addressed in this work revolve around how nanoconfinement and surface chemistry modify these interactions and how these altered interactions subsequently influence gas cluster formation. Given that nanoconfinement alters many physicochemical and thermodynamic properties of the confined species compared to their characteristics in a bulk state, [28][29][30][31][32][33][34][35][36] it is reasonable to assume that nanoconfinement significantly enhances or suppresses these interactions, which is ultimately reflected in clustering of gas molecules.…”
Gas molecule clustering within nanopores holds significance in the field of nanofluidic, biology, gas adsorption/desorption, and geological gas storage. However, the intricate roles of nanoconfinement and surface chemistry that govern...
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