Hydraulic
fracturing technology is the most important stimulate
method to develop unconventional oil and gas resources. The incomplete
flowback of the fracturing fluid causes great seepage resistance for
hydrocarbon production. Adding cleanup additive composed of surfactant
is an effective method to increase the flowback rate, which is more
closely related to the oil/water interfacial tension of the cleanup
additive. Therefore, the surface tension and interfacial tension of
sodium p-perfluorononenyloxybenzenesulfonate and
alkanolamide were studied in this work. The compounding system exhibited
high interfacial activity, and even the interfacial tension can reach
an ultralow state. In addition, the flowback experiments were conducted
in tight cores with a permeability of 0.05 × 10–3μm2, and the flowback rate increased from 42% (interfacial
tension of 1.56 mN/m) to 55.17% (interfacial tension of 0.0074 mN/m).
Therefore, from the perspective of increasing the flowback rate, the
lower interfacial tension of the residual fluid in hydraulic fracturing
stimulation should be preferred. Furthermore, the mechanism of the
surfactant compounding system to reduce the interfacial tension was
revealed by studying the interfacial dilatational rheology (interfacial
dilatation modulus), interfacial water molecule content (interfacial
free hydroxyl), and interfacial assembly behavior (molecular dynamics
simulation). The results provide a reference for the study of oil/water
interfacial behavior of surfactant compounding system and provide
an alternative cleanup additive for fracturing fluid used in unconventional
hydrocarbon production.