The field emission from GaN particles has been demonstrated successfully for the first time. The novel field emitting device has a simple structure consisting of an electrically conductive polymer layer and GaN particles spread randomly on it. The GaN particles used for this device, which were synthesized in advance by the two‐stage vapor phase method, have vertices and ridges formed by well‐developed crystal planes. The electron emission started at an electric field of about 20 V/μm, and the current reached 10 nA at 28 V/μm. The maximum current density was 0.26 mA/cm2at 43 V/μm. The Fowler‐Nordheim (F‐N) plot of the I ‐V data indicated that the observed electron emission is originated from the F‐N tunneling. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)