“…Several methods to fabricate Au tips have been developed over decades, mainly including the following: (1) electrochemical etching, − ,− , (2) chemical polishing, (3) ion milling, (4) cathode sputtering, (5) whisker growth, − and (6) mechanical shaping. − Among these, electrochemical etching, in which a metal wire is anodically dissolved in an electrolyte, is widely used because of its low cost and easy operation. In previous studies, a two-electrode electrochemical system consisting of a working electrode (WE) and a counter electrode (CE) has been applied to produce Au tips (Figure a).…”