In this paper, we report on the magnetic properties of isolated nanoparticles and
interacting nanochains formed by the self-assembly of Ni nanoparticles. The magnetic
properties were studied using superconducting quantum interference device (SQUID)
magnetometry and magnetic force microscopy (MFM). We demonstrate that single-domain
Ni nanoparticles spontaneously form one-dimensional (1D) chains under the influence of an
external magnetic field. Furthermore, such magnetic field-driven self-assembly in
conjunction with surface templating produces regular arrays of 1D nanochains with
antiferromagnetic intra-chain order. The antiferromagnetic order, which is in striking
contrast to what is found for non-interacting nanoparticle assemblies within the chains, can
be evidenced from MFM and SQUID measurements.