Fibrous Bundles in Biomorph Systems: Surface‐Specific Growth and Interaction with Microposts

Abstract

Biomorphs are polycrystalline assemblies that form when barium, silicate, and carbonate ions react in basic solutions. Their micrometer‐scale morphologies include leaf‐like sheets, helices, and cones, while their nanoscale architecture is based on co‐aligned witherite nanorods. We report a biomorph shape that resembles hair strands that smoothly curl into spirals or twisting fiber ribbons. They can thicken through continuous fractal‐like branching or abrupt events in which fibers split simultaneously. Raman and energy dispersive X‐ray spectroscopy as well as optical polarization microscopy reveal that their composition is very similar to classical biomorphs. They are most abundant in the absence of glass substrates and at high pH values. However, if a glass surface is covered by a thin SU‐8 resin layer, their growth is observed and photolithographically produced SU‐8 posts serve as nucleation sites. The hair‐like structures can detach resin posts from the glass surface and reposition them due to continued growth at the hair‐resin interface. Collisions of growing biomorph sheets with SU‐8 posts result in overgrowth or a sheet‐to‐hair transition.

Light-controlled morphological development of self-organizing bioinspired nanocomposites

“…21–27 This bioinspired reaction yields a wide diversity of shapes and symmetries such as vases, helices and coral-like forms that can be further sculpted and patterned by controlling the reaction conditions. 28–32 These morphologies show optical properties such as waveguiding and polarization. 33 Moreover post-process surface functionalization, 34–36 and ion exchange reactions have been developed towards a wide range of chemical compositions to introduce optoelectronic, 37,38 catalytic, 39 and magnetic 40 functionalities with preservation of the initial morphology.…”