Rhenium disulfide (ReS 2 ), a member of group VII transition metal dichalcogenides (TMDs), has attracted increasing attention because of its unique distorted 1T structure and electronic and optical properties, which are much different from those of group VI TMDs (MoS 2 , WS 2 , MoSe 2 , WSe 2 , etc.). It has been proved that bulk ReS 2 behaves as a stack of electronically and vibrationally decoupled monolayers, which offers remarkable possibilities to prepare a monolayer ReS 2 facilely and offers a novel platform to study photonic properties of TMDs. However, due to the large and layer-independent bandgap, the nonlinear optical properties of ReS 2 from the visible to midinfrared spectral range have not yet been investigated. Here, the band structure of ReS 2 with the introduction of defects is simulated by the ab initio method, and the results indicate that the bandgap can be reduced from 1.38 to 0.54 eV with the introduction of defects in a suitable range. In the experiment, using a bulk ReS 2 with suitable defects as the raw material, a few-layered broadband ReS 2 saturable absorber (SA) is prepared by the liquid phase exfoliation method. Using the as-prepared ReS 2 SA, passively Q-switched solid-state lasers at wavelengths of 0.64, 1.064, and 1.991 μm are investigated systematically. Moreover, with cavity design, a femtosecond passively modelocked laser at 1.06 μm is successfully realized based on the as-prepared ReS 2 SA for the first time. The results present a promising alternative for a rare broadband optical modulator and indicate the potential of ReS 2 in generating Q-switched and mode-locked pulsed lasers. It is further anticipated that this work may be helpful for the design of 2D optoelectronic devices with variable bandgaps.