Three gratings are observed during holographic recording in Bi 4 Ti 3 O 12 : There is a primary photoinduced grating with fast response and a dephasing of /2 with respect to the light pattern. It is compensated for by a complementary charge grating with much slower response. The third grating identified by phase-shift experiments is an absorption grating. At an intensity of about 0.5 W/cm 2 , a peak refractive-index change of ⌬nϭ1.8ϫ10 Ϫ5 is achieved with a response time constant 1 ϭ40 ms. The mobility-lifetime product of the charges responsible for the primary grating is R1 ϭ7.0ϫ10 Ϫ12 cm 2 /V. The conductivity of the complementary charges is much smaller than that of the primary charges, which makes it possible to prolong the readout time of the recorded holographic grating considerably.