Ferrocene

Marr, G.; Rockett, B. W.

doi:10.1016/0022-328x(86)82005-8

Cited by 12 publications

(4 citation statements)

References 128 publications

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“…Toniolo, Maggini and co-workers prepared a nonapeptide with a 3 10 -helical conformation, in which two tyrosine phenol rings were esterified with ferrocenecarboxylic acid. [198][199][200] These synthetic helical peptides were shown to have a hydrophobic binding cavity, which can serve as an efficient host for [60] fullerene.…”

Section: Other Methods For Labeling the C-terminusmentioning

confidence: 99%

“…Very recently, Salmain and Jaouen published a review on the covalent labeling of proteins with organometallic complexes . In a series of annual surveys on ferrocene in the Journal of Organometallic Chemistry , − one chapter was usually devoted to biological applications of this particular organometallic compound. Two older reviews on the biological chemistry of metallocenes have appeared. , More specialized reviews cover related aspects of ferrocene chemistry, such as, for instance, applications of the compound in glucose biosensors and bioelectronics. , Very recently, an excellent Russian review on ferrocene-containing nucleic acids was published …”

Section: Introductionmentioning

confidence: 99%

“…46 Very recently, Salmain and Jaouen published a review on the covalent labeling of proteins with organometallic complexes. 47 In a series of annual surveys on ferrocene in the Journal of Organometallic Chemistry, [48][49][50][51][52][53][54][55][56][57][58][59][60][61][62][63][64][65] one chapter was usually devoted to biological applications of this particular organometallic compound. Two older reviews on the biological chemistry of metallocenes have appeared.…”

Section: Introductionmentioning

confidence: 99%

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Bioorganometallic Chemistry of Ferrocene

2004

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5944 2.4. Other Attachment Methods 5945 2.4.1. Sonogashira Coupling 5945 2.4.2. Other Methods for Labeling the C-Terminus 5946 2.4.3. Other Methods for Labeling the N-Terminus 5947 2.4.4. Labels for the Thiol Group in Cysteine 5947 2.4.5. Miscellaneous 5947 2.5. Application of Ferrocene Compounds in Peptide Synthesis 5948 2.5.1. The Ferrocenylmethyl (Fem) Group as a Protecting Group 5948 2.5.2. Peptide Synthesis via Four-Component Reactions with Ferrocene Alkylamines 5949 3. Conjugates of Ferrocene with Proteins 5950 3.1. Redox Proteins 5950 3.1.1. Glucose Oxidase (GOD) 5950 3.1.2. D-Amino Acid Oxidase (DAAO) 5953 3.1.3. Cytochrome P450 cam 5953 3.1.4.

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Section: Other Methods For Labeling the C-terminusmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Bioorganometallic Chemistry of Ferrocene

2004

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“…A recent survey of ferrocene chemistry has appeared [ 476 ]; additions to techniques developed for functional-group interconversion involve some ferrocene derivatives.…”

Section: Miscellaneous Recent Resultsmentioning

confidence: 99%

New chemical and stereochemical applications of organoiron complexes

Fatiadi

1991

J. RES. NATL. INST. STAN.

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The objective of this review is to provide a current overview of the rapidly developing chemistry of organometallic complexes and particularly organoiron complexes useful in asymmetric and stereoselective reactions. Also covered are stereoselective reactions of α, β-unsaturated acyl ligands bound to the chiral auxiliary [(η5-C5H5) Fe(CO)(PPh3)] and new applications of organoiron complexes in the synthesis of natural products. The mechanistic aspects and stabilizing effects of the Fe(CO)3 group for alkenes or conjugated dienes are discussed. A brief summary of recent work on the special role of iron in biological reactions is also included.

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An iron–organic polymeric smoke suppressant for poly(vinyl chloride)

Neuse

Woodhouse

Montaudo

et al. 1988

Applied Organom Chemis

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The incorporation of a polyCferrocene-1, 2 (1, 3 1, 1')diylmethylenel fraction with = 2100 as a smoke suppressant additive into both unplasticized and di(2-ethy1hexyl)phthalate-plasticized, calcium carbonate-filled poly( vinyl chloride) (PVC) compositions entails appreciable reductions in smoke evolution during combustion tests relative to unmodified formulations. Best results, with smoke density reductions in the range 25-80%, are obtained at the 3% loading level, with higher additive concentrations causing no further improvements. The findings of this study may have implications on the design of other polymeric engineering materials exposed to potential fire hazards.Keywords: Polyferrocene, smoke suppressant, poly(viny1 chloride), PVC, smoke density, maximal optical density material and evaporate from the surface 2 e 9 3 on long-term storage or under conditions of slow build-up of a high-temperature environment as realized in certain fire situations, which may lead to additive depletion in the most critical phase of pyrolytic degradation and combustion.As part of a comprehensive program to develop ferrocene-containing smoke suppressants possessing structures incapable of migration and volatilization in hot environments, the present study is concerned with the incorporation of a polymeric ferrocene compound 1 into PVC compositions and an evaluation of its smokesuppressing properties.I& J. 1

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Ferrocene

Cited by 12 publications

References 128 publications

Bioorganometallic Chemistry of Ferrocene

Bioorganometallic Chemistry of Ferrocene

New chemical and stereochemical applications of organoiron complexes

An iron–organic polymeric smoke suppressant for poly(vinyl chloride)

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