Ferrocene-containing polymers

Neuse, Eberhard W.; Koda, Kazuko

doi:10.1016/s0022-328x(00)88800-2

Cited by 10 publications

(2 citation statements)

References 4 publications

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“…0 Average of more than ten measurements at 21°. 6 Ratio of reagents in the synthesis of the oxidized polymer, P = polymer, BQ = benzoquinone, and HBF4. The solvent in all cases was THF.…”

Section: T H Imentioning

confidence: 99%

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Organic solid state. VII. Semiconducting polymers. Mixed valence ferrocene-ferricenium polymers

Cowan¹,

Park²,

Pittman³

et al. 1972

J. Am. Chem. Soc.

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“…0 Average of more than ten measurements at 21°. 6 Ratio of reagents in the synthesis of the oxidized polymer, P = polymer, BQ = benzoquinone, and HBF4. The solvent in all cases was THF.…”

Section: T H Imentioning

confidence: 99%

“…The same polyferrocenylene sample was used for all these studies. 6 After preparation by the polyrecombination technique some oxidized Fe units remain after work-up. The amount was estimated by uv measurements.…”

Section: T H Imentioning

confidence: 99%

Organic solid state. VII. Semiconducting polymers. Mixed valence ferrocene-ferricenium polymers

Cowan¹,

Park²,

Pittman³

et al. 1972

J. Am. Chem. Soc.

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The Synthesis of Substituted Ferrocenes and other π‐Cyclopentadienyl‐Transition Metal Compounds

Bublitz

Rinehart

2011

Organic Reactions

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The discovery of dicyclopentadienyliron (ferrocene) in 1951 led to the development of an entirely new area of organometallic chemistry that of the pi‐metallohydrocarbons. Representative compounds are the pi‐metalloarenes such as dibenzenechromium, the pi‐methallopseudoarenes such as ferrocene, and the pi‐metalloolefin complexes such as butadiene iron tricarbonyl Since there is a great amount of literature available at this time, the treatment here is limited to three dimensions: to include only compounds containing cyclopentadienyl rings, of these to include only those which have shown to undergo aromatic substitution,reactions and within this group only synthetic aspects of their chemistry. This nearly restricts the discussion to syntheses of substituted ferrocenes.

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Ferrocene‐containing polymers. XIII. Polymeric compounds possessing carboxyphenyl side groups

Neuse¹,

Koda²

1966

J. Polym. Sci. A‐1 Polym. Chem.

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synopsis s an extension of earlier work on the condensation of ferrocene with aldehydes, the ycondensation of ferrocene with p and o-carboxybenzaldehyde is described. While, he former case, regular polycondensation occurs giving rise to a polymer composed of ocenylene and Pcarboxybenzal units, a deviation from this route is observed in the arboxybenzaldehyde case, where a polymer containing both carbaxybenzal qnd 3,3halide bridging units between the ferrocenylene groups is formed instead. This unected behavior can be accounted for by a hydride abstraction mechanism. In supt of the polymer structure proposed, 3-ferrocenylphthalide and 3,3-diferrocenylhalide are isolated as intermediates or by-products. In both polymer series, numberrage molecular weights up to 3000 (unsubfractionated) are measured. The polymers soluble in a number of organic solvents and can be cured with epoxides.

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Ferrocene-containing polymers

Cited by 10 publications

References 4 publications

Organic solid state. VII. Semiconducting polymers. Mixed valence ferrocene-ferricenium polymers

Organic solid state. VII. Semiconducting polymers. Mixed valence ferrocene-ferricenium polymers

The Synthesis of Substituted Ferrocenes and other π‐Cyclopentadienyl‐Transition Metal Compounds

Ferrocene‐containing polymers. XIII. Polymeric compounds possessing carboxyphenyl side groups

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