Balancing thermal
and visual comfort in buildings necessitates
effective insulation to counteract heat loss and gain, especially
with temperature variances. One promising approach is to combine phase
change materials, such as poly(ethylene glycol) (PEG), with high-performance
insulators like silica aerogel (Siag). To bolster opto-thermal
performance in building envelopes, we introduce a smart insulation
composite material through PEG integration, i.e., PEGalyation with
Siag. Central to this thermal behavior is the PEG’s
phase change properties, which foster a shape-stabilized framework
with Siag through their porous confinement. Preliminary
observations indicate notable capabilities of obstructing near-infrared
light while preserving satisfactory visible transparency. An optimized
Siag@PEG composite with 5% loading of PEG has the visible
range transmission of ∼92%, a decrease of ∼72% in thermal
conductivity which is lower than pure glass and PEG, leading to a
temperature dependent switchable hydrophobic to hydrophilic wettability
characteristics. As a prototype window, the thermal performance evaluation
of the synthesized composite, through experimental and computational
studies, shows a decrease in indoor temperature of ∼20% with
a higher temperature difference of ∼20 °C between outdoor
and indoor weather conditions. This lightweight composite can act
as sponge media to fill inside the double-paned window and for retrofitting
existing glazing to boost the energy efficiency of buildings with
facile manufacturing and scalability.