Spectral and luminescent properties of recently synthesized compounds of a class of hydroporphyrazines, triarenotetraazachlorins, in polyvinylbutyral films have been studied. Fluorescence lifetimes have been measured in film and in solution. Fluorescence quantum yields have been estimated. It is found that annelation of aromatic rings to the pyrrole rings of the tetraazachlorin macrocycle enhances fluorescence. Quantum-chemical optimization of the geometrical structures of the free-base 1,2-trinaphthotetraazachlorins has been carried out using the AM1 method. The two isomers were shown to be highly non-planar. Spectral hole burning in absorption bands of both this compound and free-base 2,3-trinaphthotetraazachlorin in polyvinylbutyral films at 5 K in the wavelength region of titanium-sapphire laser radiation is possible and is ascribed to NH-photoisomerization.Introduction. Existing technology for amplifying femtosecond pulses that is based on their expansion and time compression before and after amplification encounters a serious problem with reproducing the time parameters of the amplified pulse (primarily the phases), which are distorted in the optical elements used in this method. Because femtosecond pulses cannot be programmed with time due to the lack of sufficiently fast modulators, as an alternative the programming can be done by changing the broad spectrum of the pulse. This should produce an equivalent result because the time and spectral coordinates are mutually interchangeable through a Fourier transform. The usual method for carrying out this procedure involves first dispersing the spectrum of the pulse with a diffraction grating in the focal plane of a lens in which a space modulator is placed (for example, a point liquid-crystalline modulus) in order to control separately and change the strength and/or phase of each frequency channel.An original approach to forming short (pico-and subpicosecond) pulses in which materials based on free bases of porphyrins that are capable of persistent spectral hole burning (PSHB) are used has been proposed [1,2]. Adaptation of the method to spectral-time holography for forming and processing ultrashort femtosecond pulses in the near-IR region (region of principal wavelengths for optical telecommunications), i.e., applicable to pulsed radiation from a titanium-sapphire laser [3][4][5], is especially interesting. The method is based on the fact that PSHB materials at very low temperatures have high spectral selectivity and are essentially frequency-selective storage devices. This means that they exhibit simultaneously properties of a spectrometer with very high resolution and a photographic plate or CCD camera. Therefore, any type of spectral information can be stored in them without needing to disperse the spectrum over a spatial coordinate. The time information contained in the spectral hologram recorded on the PSHB material can be read as an echo-signal arising from diffraction of the short reading pulse on the spectral lattice. Thus, the echo-signal carries info...