Features of self-propagating high-temperature synthesis of spinel pigments

Radishevskaya, N. I.; Lvov, O. V.; Касацкий, Н. Г.; Chapskaya, A. Yu.; Лепакова, O. K.; Китлер, В. Д.; Naiborodenko, Yu. S.

doi:10.1134/s001050821201008x

Cited by 7 publications

(2 citation statements)

References 3 publications

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“…Owing to their thermal, chemical and solar instability, organic coloring materials are limited by short-term applications. Spinel pigments are generally stable with respect to sunlight, heat and environmental changes (Radishevskaya et al , 2012).…”

Section: Introductionmentioning

confidence: 99%

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An investigation on the synthesis of nickel aluminate

Frolovа¹

2019

PRT

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Purpose The purpose of this paper is to study the process of coprecipitation of polyhydroxocomplexes of nickel and aluminum from solutions of nickel (Ni) (II) sulfate and aluminum (Al) (III) sulfate with caustic soda and to study the conversion process to nickel aluminate and to check its properties. Design/methodology/approach For the thermodynamic analysis of the precipitation process, the software package MEDUSA was used. The dependences of the electrical conductivity, pH and residual concentrations as functions of the OH/Me ratio were obtained. Using X-ray phase analysis, spectroscopic analysis and derivatographic analysis, the properties of the products obtained were studied. The effects of OH/Me ratio and molar ratio cation of reagents on the physicochemical properties of the products were analyzed. Findings The paper deals with the results of theoretical and experimental research on the synthesis pigments of blue and green colors based on Ni-Al spinel. The influence of the molar ratio cation content on optical and color characterise of pigments were studied. Originality/value The original complex method of studying the processes of co-precipitation of cations in the form of hydroxides is proposed. pH precipitation of aluminum hydroxide and nickel are different. It is interesting to study their co-precipitation. The resulting single-phase product is a precursor of nickel aluminate over a wide range of cation ratios. The dependences of the electrical conductivity, pH and residual concentrations as functions of the OH/Me ratio were obtained.

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Section: Introductionmentioning

confidence: 99%

“…Spinels can form solid solutions with cation – chromophore. In addition, oxides exhibit the thermal and chemical stability required for the application of a pigment (Radishevskaya et al , 2012).…”

Section: Introductionmentioning

confidence: 99%