Fe(III)-Based Phenylsilsesquioxane/Acetylacetonate Complexes: Synthesis, Cage-like Structure, and High Catalytic Activity
Alexey N. Bilyachenko,
Victor N. Khrustalev,
Pavel V. Dorovatovskii
et al.
Abstract:Unprecedented iron-based silsesquioxane/acetylacetonate complexes were synthesized. The intriguing cage-like structure of compounds is alkaline metal-dependent: the Fe 2 Li 2 complex includes condensed Si 6 -silsesquioxane and four acetylacetonate ligands; the Fe 4 Na 4 complex exhibits two cyclic Si 4 -silsesquioxane and eight acetylacetonate ligands, while the Fe 3 K 3 complex features two cyclic Si 3 -silsesquioxane and six acetylacetonate ligands. The latter case is the very first observation of small trim… Show more
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