Fe-Based metal–organic frameworks as functional materials for battery applications

Abstract

This review presents a comprehensive discussion on the development and application of pristine Fe-MOFs in lithium-ion batteries, sodium-ion batteries, potassium-ion batteries, metal–air batteries and lithium–sulfur batteries.

Intercalation pseudocapacitance in 2D N-doped V2O3 nanosheets for stable and ultrafast lithium-ion storage

“…11,12 To this end, numerous anode materials have been developed including metal oxides, alloys, and their composites. [12][13][14] However, the majority of them suffer from volume expansion during the lithiation/delithiation process, which gradually leads to stress accumulation and then crushing. 15 Consequently, it is of great significance to develop high-performance anode materials for Li-ion batteries.…”

A novel flame-resistant separator for high performance lithium–sulfur batteries

“…So far, many new functional separators have shown great potential in practical battery applications. By introducing functional materials coatings on the separator, including polymer materials, carbon-based materials, 9-12 inorganic oxides, 13,14 catalytic polar metal compounds 15 and metal/covalent organic frameworks, [16][17][18][19][20] the specific capacity, cycle stability, multiplier performance, Coulomb efficiency and safety of LSB can be significantly improved. There are two main preparation technologies: one is to use the vacuum suction filtration and barrier layer which were placed on the surface of the PP separator, but this method takes a long time, especially for nanomaterials; the other one would be make a paste of barrier with binder and coat on the PP separator, yet the thickness of the layer cannot be controlled.…”

Completely suppressed high-voltage phase transition of P2/O3-Na0.7Li0.1Ni0.1Fe0.2Mn0.6O2viaLi/Ni co-doping for sodium storage

“…[1][2][3][4][5][6][7] In general, the energy density and cycling life of SIBs are highly dependent on cathode materials. [8][9][10][11] Among various cathode materials, P2-type Fe, Mn-based layered oxides for SIBs have been attractive owing to the huge abundance, eco-friendliness, and low price of Fe and Mn. [12][13][14][15] In particular, P2-Na 2/3 Fe 1/2 Mn 1/2 O 2 possesses a high capacity of 190 mA h g −1 within the potential range from 1.5 to 4.3 V, benefitting from those two redox couples of Fe 3+ /Fe 4+ and Mn 3+ /Mn 4+ .…”