A new chemical passivation technique, which contained 20 g/L hydrogen peroxide, 3.75 g/L sodium silicate, 1.25 g/L sodium carbonate, 3.75 g/L lactic acid and 0.75 g/L 8-hydroxyquinoline, was used to modify 316 stainless steel with Ag coating (Ag-coated 316SS) as PEMFC bipolar plates. The results indicated that the compact passive film had been obtained on the surface of Agcoated 316SS. The passivation process could not only increase contact angle (from 58• to 104 • ) but also decreased pinhole defects of Ag-coated 316SS. Electrochemical test manifested that the passivation process could reduce Ag-coated 316SS's double layer capacitance (C d ), and increase its charge transfer resistance. So, it provided significant protection against corrosion for Ag-coated 316SS in PEMFC environment.