Asphalt
is a typical self-healing material, but the healing process
is rather inefficient. Therefore, melamine–urea–formaldehyde
(MUF) microcapsules containing rejuvenator were fabricated to enhance
the self-healing ability of asphalt. Optical and scanning electronic
microscopy (SEM) morphologies showed that the prepared microcapsules
were intact, and the outer surface of the microcapsule was rough,
with both observations were beneficial for the interaction between
asphalt and microcapsules. Microcapsules were mixed with asphalt by
a proportion of 3 wt %, and almost all the microcapsules were kept
intact even when experiencing 160 °C high temperature and mechanical
agitation. It is noted that microcapsules were distributed homogeneously,
which were highly likely to release rejuvenator after meeting with
microcracks. A ductility self-healing test, along with fluorescence
microscopy observations, was conducted to demonstrate how MUF microcapsules
performed in asphalt. The test found that microcapsules were broken
by the fracture energy at the tip of the crack, and thus a rejuvenator
channel among microcapsules and cracks was formed to let the rejuvenator
capillary-flow into the crack before the closure of microcracks. The
DSR (dynamic shear rheometer) fatigue–healing–fatigue
test and direct tensile test were further carried out to evaluate
the healing efficiency of asphalt binder containing different contents
of microcapsules.