“…Six types of polymer films were employed as common and practical substrates in flexible electronics: polyethylene naphthalate (PEN, Teonex Q51, Toyobo Co., Ltd., Japan), polyethylene terephthalate (PET; Lumirror S10, Toray Industries Inc., Japan), PVC (107-16601 and 107-16602, KOKUGO Co., Ltd., Japan), PC (Lupilon NF-2000, Mitsubishi Gas Chemical Inc., Japan), cycloolefin (COP, ZeonorFilm ZF-14, ZEON Corp., Japan), and PS (Santoclear, Mitsubishi Chemical Corp., Japan). − The direction of the polymer main chain orientation was identified by polarized optical microscopy (POM; BX50, Olympus Corp., Japan) and attenuated total reflectance infrared spectroscopy (ATR-IR; FTIR-6600, JASCO Corp., Japan), as shown in the previous report . The polymer films with various thicknesses (50–300 μm) were used for the bending fatigue test after being cut into dimensions of 40 mm length and 30 mm width according to the polymer main chain orientation.…”