Various surface treatments
have been developed on titanium and
its alloy to improve their tribological properties. However, for some
components, only specific surfaces need to be hardened rather than
the whole surfaces. This study develops a duplex heat treatment including
selective surface hardening by prepainting TiO2 powders
and thermal oxidation. It is found that the TiO2 powder
layer can be used as an oxygen reservoir for boosting diffusion treatment
at temperatures of 800–900 °C. The abundance of oxygen
provides high potential and accelerates the diffusion process, deeply
hardening the surface case. Moreover, the duplex treatment is optimal
for selectively hardened surfaces with high load-bearing capacity
and much improved tribological properties. Prepainting the surfaces
that need to be hardened is easy to operate and has good potential
to be applied in industry.