Fate of Macronutrients in Water Treatment of Digestate Using Vibrating Reversed Osmosis

Abstract

In the transition from a fossil to a bio-based economy, it has become an important challenge to maximally recuperate and recycle valuable nutrients coming from manure and digestate processing. Membrane filtration is a suitable technology to separate valuable nutrients in easily transportable concentrates which could potentially be re-used as green fertilizers, in the meantime producing high quality water. However, traditional membrane filtration systems often suffer technical problems in waste stream treatment. The aim of this study was to evaluate the performance of Vibratory Shear Enhanced Processing (VSEP) in the removal of macronutrients (N, P, K, Na, Ca, Mg) from the liquid fraction of digestates, reducing their concentrations down to dischargeable/re-usable water. In addition, the re-use potential of VSEP-concentrates as sustainable substitutes for fossil-based mineral fertilizers was evaluated. Removal efficiencies for N and P by two VSEP filtration steps were high, though not sufficient to continuously reach the Flemish legislation criteria for discharge into surface waters (15 mg N l -1 and 2 mg P l -1 ).Additional purification can occur in a subsequent lagoon, yet further optimization of the VSEP filtration system is advised. Furthermore, concentrates produced by one membrane filtration step showed potential as N-K fertilizer with an economic value of € 6.3 ± 1.1 ton -1 Fresh Weight (FW).Further research is, however, required to evaluate the impact on crop production and soil quality by application of these new potential green fertilizers.

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Review of high recovery concentrate management options

“…The opposite scenario is observed without vibration where new particles are generated faster than particle growth. A study by Vaneeckhaute et al in 2012, applied VSEP technology to remove macronutrients from digestate in order to reuse concentrate as inorganic fertilizers with high nutrient availability [68]. Macronutrients such as Nitrogen (N), Phosphorus (P), Potassium (K), Sodium (Na), Calcium (Ca) and Magnesium (Mg) are required from liquid fractions of digestate and concentration is lowered to a reusable range.…”

“…Low salt content and total hardness indicate that permeate within the lagoon has potential for re-use in high quality applications. Even though recovery was high across the two stages, VSEP performance is limited by technical and mechanical problems that cause instability and exceeding of statutory levels in the lagoon [68].…”

Performance of a vibratory shear membrane filtration system during the treatment of magnetic ion exchange process concentrate

“…Vaneeckhaute applied VSEP technology to remove macronutrients from digestate, a product produced from co-digestion of animal manure [18]. The primary functionality of the VSEP was to remove macronutrients ranging from nitrogen, phosphorus, potassium, sodium, calcium and magnesium.…”