Irradiations of vanadium and molybdenum were performed at liquid‐hydrogen temperature with various fluences of fission neutrons. The results of the high‐dose irradiation served to calculate the spontaneous recombination volumes of the two metals: α rMo = 55 at. vol., α rV = 690 at. vol. when using the model of Lück and Sizmann, and α r0Mo = 210 at. vol., α r0V = 810 at. vol. when applying that of Balarin and Hauser. The large differences between the recombination volumes for the two b.c.c. metals are an argument against a simple lattice‐structure dependence of αr. The decisive role of ϱF, the electrical resistivity of a Frenkel pair, is discussed in detail. The recovery spectra of both, V and Mo, were determined between 24 and 440 °K, with the radiation‐induced defect concentration as parameter. A tentative interpretation of the various annealing stages is given.