We propose a supervised learning framework for computing solutions of multi-parametric Mixed Integer Linear Programs (MILPs) that arise in Model Predictive Control. Our approach also quantifies sub-optimality for the computed solutions. Inspired by Branch-and-Bound techniques, the key idea is to train a Neural Network/Random Forest, which for a given parameter, predicts a strategy consisting of (1) a set of Linear Programs (LPs) such that their feasible sets form a partition of the feasible set of the MILP and (2) a candidate integer solution. For control computation and sub-optimality quantification, we solve a set of LPs online in parallel. We demonstrate our approach for a motion planning example and compare against various commercial and open-source mixedinteger programming solvers.* denotes equal contribution. SHN and FB are with the Model Predictive Control lab, University of California, Berkeley. LR and LG are with University of Sannio.