Current-voltage dependences (IV-D) of ITO/melanin layer/ITO structures were studied. Hysteresis voltages of quasistatic IV-D are near to water decomposition potentials. Short wet air pulse gives rise to displacement current maxima on dynamic IV-D. Modelling of IV-D by series-parallel RC-circuit with Zener diodes was performed. As a reason reversible ionic transfer and ferroelectric polarization are considered.