Applying an expanding cascaded arc thermal plasma beam deposition technique, amorphous fluorohydrogenated carbon (a-C:H,F) layers were deposited from acetylene (C,H,) and tetrafluoromethane (CF,). Deposition of the layers was monitored in situ by HeNe ellipsometry and the layers were analyzed ex situ by Fourier transform IR spectroscopy.Tt is found that the growth rate of the layers is independent of the addition of the CF, precursor. However, the structure of the layers is influenced by the addition of CF,. It is found that the extinction coefficient decreases with increasing CF, flow. The composition of the layers is changed with respect to the bonding types in the layers. The addition of CF, leads to incorporation of F in the layers and also to the appearance of sp' CH bonds, which implies modification of the layers by CF,.