Fast and Mild Palladium(II)‐Catalyzed 1,4‐Oxidation of 1,3‐Dienes via Activation of Molecular Oxygen with a Designed Cobalt(II) Porphyrin.

Abstract

Cyclohexane derivatives Q 0040Fast and Mild Palladium(II)-Catalyzed 1,4-Oxidation of 1,3-Dienes via Activation of Molecular Oxygen with a Designed Cobalt(II) Porphyrin. -The chiral center in the ligand does not lead to asymmetric induction in the title reaction. -(VERBOOM, R. C.; SLAGT, V. F.; BAECKVALL*, J.-E.; Chem. Commun. (Cambridge) 2005, 10, 1282-1284; Dep. Org. Chem., Arrhenius Lab., Univ. Stockholm, S-106 91 Stockholm, Swed.; Eng.) -M. Paetzel 30-058