Carbon-based nanomaterials have always
been in high demand because
of their efficient adsorption capabilities. Herein, we synthesized
water-dispersible carboxylic acid-terminated carbon nanoflakes (CNFs)
by simple acid treatment in aqueous solution of glucose. The as-synthesized
CNFs have been used for the adsorption of multiple water-soluble cationic
dyes and even from a mixture of spiked industrial wastewater. Here,
we have used six water-soluble model dyes methylene blue (MB), crystal
violet (CV), rhodamine B (RhB), congo red (CR), methyl orange (MO),
and metanil yellow (MY) for adsorption studies. CNFs show significant
adsorption capacity toward cationic dyes (MB, CV, and RhB) compared
to anionic dyes (CR, MO, and MY). Selectivity in adsorption of cationic
dyes on negatively charged CNFs adsorbents has occurred via electrostatic
interaction. The adsorption capacities of CNFs toward three cationic
dyes (MB, CV, and RhB) are ∼148, ∼132, and ∼118
mg g –1, respectively. More importantly, it is observed
that CNFs have performed as better adsorbents than the well-known
commercially available activated charcoal for the tested dyes. The
adsorption process has been studied by varying different regulating
parameters such as pH of the solution, initial dye concentration,
temperature, and the concentration of CNFs and analyzed in terms of
kinetic and isotherm models. Moreover, the adsorbed dyes could be
desorbed completely from nanoflake surfaces and are efficient for
multicyclic use.