2006
DOI: 10.1103/physreva.73.042711
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Fano interference and cross-section fluctuations in molecular photodissociation

Abstract: We derive an expression for the total photodissociation cross section of a molecule incorporating both indirect processes that proceed through excited resonances, and direct processes. We show that this cross section exhibits generalized Beutler-Fano line shapes in the limit of isolated resonances. Assuming that the closed system can be modeled by random matrix theory, we derive the statistical properties of the photodissociation cross section and find that they are significantly affected by the direct process… Show more

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Cited by 14 publications
(25 citation statements)
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References 39 publications
(42 reference statements)
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“…It is the dip of the spectral form factor discussed in [44]. It has also been investigated in molecules [43,[45][46][47][48][49], random matrices [50][51][52][53][54], microwave billiards [55,56] and disordered spin models [19]. Here, we extend these studies to clean and disordered spin-1/2 models.…”
Section: Introductionmentioning
confidence: 86%
See 1 more Smart Citation
“…It is the dip of the spectral form factor discussed in [44]. It has also been investigated in molecules [43,[45][46][47][48][49], random matrices [50][51][52][53][54], microwave billiards [55,56] and disordered spin models [19]. Here, we extend these studies to clean and disordered spin-1/2 models.…”
Section: Introductionmentioning
confidence: 86%
“…Contrary to signatures of chaos associated with the spacings of neighbouring levels, the level number variance detects long-range correlations between the eigenvalues. Correlations between energy levels are the source of the drop of P ini (t) belowP ini , which is known as the correlation hole [43,[45][46][47][48][49][50][51][52][53][54][55][56]. The correlation hole occurs at long times and disappears as we approach the Heisenberg time (the inverse of the mean level spacing [73]).…”
Section: (Iii) Survival Probability and Correlation Holementioning
confidence: 99%
“…But before saturating, the dynamics resolves the discreteness of the spectrum. In the case of chaotic systems, the correlations between the eigenvalues are reflected in the evolution of the survival probability in the form of a dip below the saturation point, known as correlation hole [38][39][40][41][57][58][59][60][61][62][63][64][65][66]. The correlation hole was studied in the context of FRM, billiards, and molecules.…”
Section: Correlation Holementioning
confidence: 99%
“…The use of complex energies allows for the combination of the energy of a resonance with its width [11]. Correspondingly, non-Hermitian Hamiltonians are commonly used to describe the dynamics of open systems [12][13][14][15][16]. In quantum optics the use of non-Hermitian Hamiltonians is put in a more rigorous form by the so-called quantum jump formalism, or Monte Carlo wave function method [12], which is equivalent to the evolution by a Markovian master equation.…”
Section: Introductionmentioning
confidence: 99%