1989
DOI: 10.1080/00380768.1989.10434733
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Factors affecting zero point of charge (zpc) of variable charge soils

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Cited by 46 publications
(34 citation statements)
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“…Sakurai et al (1989) verified that the Al o exerted the greatest impact on the zero point of charge (ZPC) values of Japanese and Thai soils, whereas Parks (1965) reported values between 7.5 and 8.0 and Perrott (1977) found a value of 9.3 for the ZPC of synthetic amorphous aluminum oxides. Considering that the phosphate adsorption occurs through exchange with single coordinated surface hydroxyls (Parfitt, 1978) and that these hydroxyls are probably the easiest ionizable ones, the minerals presenting higher ZPC values would have a great number of these surface hydroxyls and therefore a greater impact on P adsorption .…”
Section: Resultsmentioning
confidence: 99%
“…Sakurai et al (1989) verified that the Al o exerted the greatest impact on the zero point of charge (ZPC) values of Japanese and Thai soils, whereas Parks (1965) reported values between 7.5 and 8.0 and Perrott (1977) found a value of 9.3 for the ZPC of synthetic amorphous aluminum oxides. Considering that the phosphate adsorption occurs through exchange with single coordinated surface hydroxyls (Parfitt, 1978) and that these hydroxyls are probably the easiest ionizable ones, the minerals presenting higher ZPC values would have a great number of these surface hydroxyls and therefore a greater impact on P adsorption .…”
Section: Resultsmentioning
confidence: 99%
“…The PZSE and op values of the variable charge soils were mainly affected by the following factors (Sakurai et al 1989); the presence of organic matter, exchangeable Al, and 2 : 1 type crystalline clay minerals which shifted the PZSE value toward a lower pH range, resulting in a higher op value, whereas, presence of amorphous materials and accumulated sesquioxides shifted the PZSE value toward a higher pH range, resulting in a lower op value.…”
Section: Physico-chemical and Mineralogical Propertiesmentioning
confidence: 99%
“…Dentre os atributos eletroquímicos, o de maior destaque para solos intemperizados das regiões tropicais é o ponto de efeito salino nulo (PESN), utilizado na descrição de fenômenos decorrentes da dupla camada elétrica de interfaces reversíveis (Sakurai et al, 1989;Alleoni & Camargo, 1994a,b;Zhang & Zhao, 1997) e na determinação de vários atributos pedológicos (Fontes et al, 2001 (Uehara & Gillman, 1981) Assim, pode-se afirmar que a densidade de carga na superfície pode ser alterada em solos com carga variável pela aplicação orientada de fertilizantes e corretivos, aumentando significativamente a CTC e, portanto, a capacidade produtiva desses solos. Uma outra característica importante acerca do PESN do solo é que ele corresponde ao ponto químico de máxima estabilidade, onde o potencial de superfície é nulo (Sposito, 1989).…”
Section: Introductionunclassified