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Solidification is a process of incorporating radioactive wastes into a solid insoluble matrix, which is the main barrier preventing radionuclides from escaping into the environment. Glass, ceramics, bitumen, cement (concrete), polymers, rubber, and so on can be used as the matrix.For medium-level wastes bitumenization and cementing processes are most widely used. In addition, for high-level wastes (10 -3 to i Ci/liter) a bitumen matrix is preferable because it is most stable with respect to leaching of radionuclides by ground waters. Up to 40-50 mass % of radioactive dry residue can be incorporated into a bitumen matrix and only 15-30% can be incorporated into a cement matrix. Above these percentages the stability of the matrix with respect to leaching drops sharply. Since a cement matrix, in contrast to a bitumen matrix, is noncombustible, in the last few years a great deal of attention has been devoted to cementing.The All of these setups are suitable for reprocessing bottoms, and the RB and KB bitumenizers can also be used to reprocess hydroxide, perlite, and ion-exchange resin sludges. Some models of all three types of bitumenizers have been checked on simulated wastes on stands at the SRICMM.A great deal of experience has been accumulated in operating setups with the RB and TB bitumenizers on real wastes. Setups with the RB-1000 bitumenizer with a capacity of 400 liters/h have been operating at the Leningrad nuclear power plants since 1984 (first setup) and since 1985 (second setup) and at the Ignalin nuclear power plant (Lithuania) since 1987. The setup with the RB-800 bitumenizer with a capacity of up to 250 liters/h has been operating since 1989 at the Kalinin nuclear power plant. On these setups the bitumen mixture is pumped into concrete compartments of the burial site, where it congeals. Setups with the RB-800 bitumenizers have been assembled at the Balakov, Roven, and Southern-Ukraine nuclear power plants. In these setups the bitumen mixture is packaged into 200-liter metal barrels. The TB-16 apparatus with a periodic-action bitumenizer with a capacity of 240 liters/h has been operating since 1978 at the Leningrad Special Industrial Group "Radon" (Sosnovyi Bor), where the burial site for the bitumen mixture is filled by pouring. The TB-and KB-type periodic-action bitumenizers with a complex of auxiliary equipment have been developed for a radiochemical plant. Setups with KB bitumenizers with a capacity of 40 liters/h have been produced for nuclear heat-generating plants.A diagram of a setup with a RB-800 bitumenizer is displayed in Fig. t. The bitumenizer 5 consists of a thin-film rotor evaporator with hinged paddles. The cubic residue and the bitumen are fed in a definite ratio by the pumps 1 and 4 with a regulatable flow rate from the tanks 2 and 3 into the bitumenizer where evaporation of the wastes and mixing with bitumen occur in a thin film. The bitumen mixture is fed by a double-auger Open-Type Joint-Stock Company "Sverdlovsk Scientific-Research Institute of Chemical Machinery Manufacture."
According to the adopted international standards, any radioactive wastes must be buried in solid or solidified form. In our country the method of bituminization is most often used for solidifying low-and medium-level radioactive wastes formed at different stages of the nuclear fuel cycle. The bituminization process is also widely used in many countries with a developed nuclear power industry. At the present time, more than 20 industrial bituminization installations are operating at nuclear power plants and in nuclear centers in the USA, France, Sweden, Finland, Japan, Belgium, Mexico, Slovakia, Latvia, and other countries.In our country bituminization installations are operating at two nuclear power plants (Leningrad and Kalinin), two PZRO (Moscow Scientific and Industrial Association "Radon" and the Lenin Special Combine) and two SPRV VMF stations [1][2][3][4]. Assembly of equipment is being completed at the Balakov nuclear power plant. Three types of bituminization equipment are now being planned and tested: rotor-film, tubular, and an auger system. The first two types are in commercial operation, and the third type has passed the stage of commercial testing at the Novovoronezh nuclear power plant. It consists of two units: a concentrator of the flow-through evaporator type (UGU-400) and a two-auger mixer . In the course of the tests technological regimes that make it possible to obtain a homogeneous bituminous compound with a degree of filling of about 40 mass % with respect to the salts of the borate-containing solutions were determined.Investigations showed that the optimal regime is one in which a salt concentrate with a boiling point of 115-120~ i.e., moisture content -15-25 mass%, flows into the mixer from the flow-through evaporator. This also makes it possible to obtain an emulsion and subsequently a homogeneous compound. For a lower moisture content of the salt melt in the intrinsic crystal-hydrate water, a bituminous emulsion (water solution-bitumen) is not formed and the quality of the compound decreases. Moreover, stratification of the compound on cooling is observed.The TB-16 tubular bituminizer has been operating for about 16 years at the Special Leningrad Combine. It consists of a short tubular evaporator with forced mixing of the mass and two augers attached to a vertical shaft. The bituminizer has a separation zone with a mechanical entrainment trap. The process of bituminization is semicontinuous: When the required quantity of bitumen is fed once at the start of the process and with gradual feeding of the salt concentrate as it evaporates. The average feed rate of the concentrate is 300 liters/h. For a warming-vapor pressure of 0.6 MPa the average productivity of the apparatus is about 190 liters/h with respect to the evaporated moisture. An emulsion is produced thanks to vigorous mixing. The process can be separated into two stages: evaporation of the main mass of the water from the bitumen emulsion in the water solution and additional evaporation of the water from the emulsion into the bitum...
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