Abstract:A Si/Ge/graphite@C composite was synthesized by ball-milling and subsequent calcination. In the figure, the long-term cycling performance is displayed and the inset image is the tap density comparison of this sample with commercial graphite.
“…It demonstrates that the Ni-CoSe 2 heterojunction accelerates redox kinetics. 46 In addition, the change in peak current density of the pristine and modied separators indicates that Ni-CoSe 2 @NC can signicantly increase capacity utilization. Tafel plots tted from the CV peaks are showed in Fig.…”
A novel Ni–CoSe2 heterojunction coated with N-doped carbon is designed to modify separators of Li–S batteries, exhibiting the synergism of suppressing shuttle effects and accelerating reaction kinetics.
“…It demonstrates that the Ni-CoSe 2 heterojunction accelerates redox kinetics. 46 In addition, the change in peak current density of the pristine and modied separators indicates that Ni-CoSe 2 @NC can signicantly increase capacity utilization. Tafel plots tted from the CV peaks are showed in Fig.…”
A novel Ni–CoSe2 heterojunction coated with N-doped carbon is designed to modify separators of Li–S batteries, exhibiting the synergism of suppressing shuttle effects and accelerating reaction kinetics.
“…6 The depletion of non-renewable resources has led to an increase in the price of oil and the cost of cars, which has led to a shi in attention from gasoline-powered vehicles to lower-cost electric vehicles. 7,8 Currently, individuals must consider range and charging speed as the two primary factors when choosing an electric vehicle. 9 Recent advances in high specic energy electrode materials have largely alleviated the challenge of range anxiety, but the focus is now on solving the problem of charging speed and environmental adaptability, such as temperature uctuation.…”
The carbon coated graphite prepared by CVD method can meet the stable cycling. The pouch cell GC-2‖LiCoO2 exhibits noteworthy durability, retaining 87% of its capacity even after 1200 cycles at a high charge/discharge rate of 5C/5C.
“…For example, X-ray diffraction (XRD) is used for studying the crystal structure and lattice spacing of materials (Connolley et al, 2020;Matras et al, 2020). Although XRD can provide structural information about crystalline materials, it is not easy to perform characterization studies on amorphous materials or materials without long-range order (Chen et al, 2024;Chen & Huang, 2023;. The pair distribution function (PDF) utilizes total scattering (Bragg and diffuse scattering) and has been used to investigate long-range disordered materials with short-range ordering (Wiaderek et al, 2013).…”
Understanding the correlation between chemical and microstructural properties is critical for unraveling the fundamental relationship between materials chemistry and physical structures that can benefit materials science and engineering. Here, we demonstrate novel in situ correlative imaging of the X-ray Compton scattering computed tomography (XCS-CT) technique for studying this fundamental relationship. XCS-CT can image light elements that do not usually exhibit strong signals using other X-ray characterization techniques. This paper describes the XCS-CT setup and data analysis method for calculating the valence electron momentum density and lithium-ion concentration, and provides two examples of spatially and temporally resolved chemical properties inside batteries in 3D. XCS-CT was applied to study two types of rechargeable lithium batteries in standard coin cell casings: (1) a lithium-ion battery containing a cathode of bespoke microstructure and liquid electrolyte, and (2) a solid-state battery containing a solid-polymer electrolyte. The XCS-CT technique is beneficial to a wide variety of materials and systems to map chemical composition changes in 3D structures.
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