2023
DOI: 10.1016/j.est.2023.107428
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Facile synthesis of mixed nickel-cobalt oxalates with composition control as high-performance electrode materials for supercapacitor

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Cited by 8 publications
(3 citation statements)
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“…At this state, a solution of oxalic acid provides H + ions to decompose the carbonate radical of the precursor salt and releases a large amount of CO 2 gas. The transition metal ions (Ni, Mn, and Co) combine with C 2 O 4 2– radicals to form precipitates, while lithium ions still exist in a solvated state and are in charge balance with C 2 O 4 2– ions. After perfectly mixing, the sample is heated at 100 °C until all water evaporates to form a solid mixture of lithium–nickel–manganese–cobalt oxalates (LiNiMnCo-ox) and an excess of oxalic acid. Step 4: The solid mixture obtained from “step 3” is calcinated at 850 °C for 10 h under an oxygen stream flowing in at a rate of 1 L min –1 .…”
Section: Methodsmentioning
confidence: 99%
“…At this state, a solution of oxalic acid provides H + ions to decompose the carbonate radical of the precursor salt and releases a large amount of CO 2 gas. The transition metal ions (Ni, Mn, and Co) combine with C 2 O 4 2– radicals to form precipitates, while lithium ions still exist in a solvated state and are in charge balance with C 2 O 4 2– ions. After perfectly mixing, the sample is heated at 100 °C until all water evaporates to form a solid mixture of lithium–nickel–manganese–cobalt oxalates (LiNiMnCo-ox) and an excess of oxalic acid. Step 4: The solid mixture obtained from “step 3” is calcinated at 850 °C for 10 h under an oxygen stream flowing in at a rate of 1 L min –1 .…”
Section: Methodsmentioning
confidence: 99%
“…In Figure 5d, the similar Nyquist plots of materials indicate the same equivalent circuit diagram of these materials. 33 The Nyquist plot of materials involved a depressed semicircle followed by a sloped line. As shown in Figure 5d, the PAN/Ag 2 S sample has a smaller Nyquist semicircle and lower charge transfer resistance (R s ) as compared to PAN nanofibers.…”
Section: Materials Propertiesmentioning
confidence: 99%
“…Efforts were made to improve the performance of supercapacitors by enhancing the reaction kinetics of electrode materials through methods such as surface engineering and atomic doping. Transition metal oxides/hydroxides have shown promise as electrode materials owing to their large specific surface area, tunable synthesis process, and low cost. Incorporating transition metals into these materials can have a synergistic effect on redox reactions, offering an effective pathway for enhancing the performance of supercapacitors. , Modification of the surfaces of transition metal oxides is a direct method for altering the electronic conductivity and reaction energy barriers, significantly impacting the energy storage and conversion ability of supercapacitors. …”
Section: Introductionmentioning
confidence: 99%