Facile synthesis of graft copolymers containing rigid poly(dialkyl fumarate) branches by macromonomer method

Sato, Eriko; Tamari, Noboru; Horibe, Hideo

doi:10.1002/pola.29499

Cited by 5 publications

(6 citation statements)

References 23 publications

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“…In addition, other copolymers including fumaric monomers, with different structural characteristics have been obtained by Sato et al [37]. The authors synthesized graft copolymer with a flexible backbone and rigid branches (Fig.…”

Section: Tablementioning

confidence: 99%

See 1 more Smart Citation

Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications

Oberti,

Cortizo

2023

European Polymer Journal

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Section: Tablementioning

confidence: 99%

“…Analysis of several PDRF by DSC revealed that most of this type of (Reproduced from [37] with John Wiley and Sons permission).…”

Section: Propertiesmentioning

confidence: 99%

Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications

Oberti,

Cortizo

2023

European Polymer Journal

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“…developed a new route toward graft copolymers containing poly(D i PrFm) branches. [ 516 ] They first synthesized a poly(D i PrFm) macromonomer by addition‐fragmentation chain transfer and subsequently copolymerized this macromonomer with ethyl acrylate.…”

Section: Polymerization Of (Meth)acrylic Monomers and Analogsmentioning

confidence: 99%

Production and Polymerization of Biobased Acrylates and Analogs

Fouilloux

Thomas

2021

Macromol. Rapid Commun.

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To prepare biobased polymers, particular attention must be paid to the obtention of the monomers from which they are derived. (Meth)acrylates and their analogs constitute such a class of monomers that have been extensively studied due to the wide range of polymers accessible from them. This review therefore aims to highlight the progresses made in the production and polymerization of (meth)acrylates and their analogs. Acrylic acid production from biomass is close to commercialization, as three different high‐potential intermediates are identified: glycerol, lactic acid, and 3‐hydroxypropionic acid. Biobased methacrylic acid is less common, but several promising options are available, such as the decarboxylation of itaconic acid or the dehydration of 2‐hydroxyisobutyric acid. Itaconic acid is also a vinylic monomer of great interest, and polymers derived from it have already found commercial applications. Methylene butyrolactones are promising monomers, obtained from bioresources via three different intermediates: levulinic, succinic, or itaconic acid. Although expensive, methylene butyrolactones have a strong potential for the production of high‐performance polymers. Finally, β‐substituted acrylic monomers, such as cinnamic, fumaric, muconic, or crotonic acid, are also examined, as they provide an original access to biobased materials from various renewable raw materials, such as protein waste, lignin, or wastewater.

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“…This is the case of rigid poly(diisopropyl fumarate), which was reacted with ethyl acrylate, given branch flexibility. [ 195 ]…”

Section: Functionalization Via Enzymatic Catalysismentioning

confidence: 99%

Enzymatic Synthesis of Polyesters and Their Bioapplications: Recent Advances and Perspectives

Hevilla

Sonseca

Echeverría

et al. 2021

Macromolecular Bioscience

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This article reviews the most important advances in the enzymatic synthesis of polyesters. In first place, the different processes of polyester enzymatic synthesis, i.e., polycondensation, ring opening, and chemoenzymatic polymerizations, and the key parameters affecting these reactions, such as enzyme, concentration, solvent, or temperature, are analyzed. Then, the latest articles on the preparation of polyesters either by direct synthesis or via modification are commented. Finally, the main bioapplications of enzymatically obtained polyesters, i.e., antimicrobial, drug delivery, or tissue engineering, are described. It is intended to point out the great advantages that enzymatic polymerization present to obtain polymers and the disadvantages found to develop applied materials.

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Facile synthesis of graft copolymers containing rigid poly(dialkyl fumarate) branches by macromonomer method

Cited by 5 publications

References 23 publications

Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications

Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications

Production and Polymerization of Biobased Acrylates and Analogs

Enzymatic Synthesis of Polyesters and Their Bioapplications: Recent Advances and Perspectives

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