FACILE SYNTHESIS OF FUNCTIONALIZED UiO-66-TYPE MOFs FOR CO2 ADSORPTION

Abstract

The metal-organic frameworks (MOFs) UiO-66-NH2, UiO-66-2,5-(OH)2, UiO-66-NO2, UiO-66-NDC, and UiO-66-BPDC were synthesized under solvothermal conditions using different functionalized organic linkers. The structures and properties of the samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy, and nitrogen adsorption-desorption isotherms. The crystal structures of these functionalized UiO-66(Zr) forms were similar. A series of functionalized UiO-66(Zr) samples were used in the adsorption of carbon dioxide (CO2). UiO-66-NH2 had the highest CO2 adsorption capacity (about 3.35 mmol g-1) due to its small polar –NH2 group. The performance of UiO-66-NH2 in CO2 adsorption at different temperatures was also determined. The amino-functionalized material possessed better adsorption properties at 273 K than at 303 K, while the CO2 working capacity of UiO-66-NH2 was fully recovered after cyclic regeneration.