Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

Abstract

Three-dimensional iodoargentate hybrids [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) (en = ethylenediamine) and [Co(dien)2(Ag2I4)]n∙nH2O (3) (dien = diethylenetriamine) were prepared in C2H5OH solvent via a one-step reaction under solvothermal conditions. In compounds...