Reduced graphene oxide (rGO)-TiO 2 nanotube (TNT) composites sensitized by Meso-tetra (4-carboxyphenyl) porphyrin (H 2 TCPP/rGO-TNT) have been synthesized successfully with improved hydrothermal and heat reflux synthesis process. The chemical structure and performances of H 2 TCPP/rGO-TNT composites have been characterized by TEM-EDS-SAED, DRS and XRD. The influences of both rGO and/or H 2 TCPP for TNT to adsorb and degrade Rhodamine-B (RhB) have been analyzed by DRS. In addition, the degradation results showed a purification of more than 93 % RhB in wastewater, which is about 4.6 times higher than that of the pure TNT. The experimental results revealed that H 2 TCPP/rGO-TNT own superior degradation activity. This phenomenon is due to the excellent photons-capture system of the H 2 TCPP, and the high photoinduced electron mobility characteristic of graphene acceptor. Thus, these materials can be employed to degrade organic pollutants, and effectively applied in wastewater quality control and its treatment.