Facile hydrosilylation of norbornadiene by silanes R3SiH and R2SiH2 with molybdenum catalysts

Hydrostannation of norbornadiene by nBu3SnH and Ph3SnH with molybdenum catalysts

“…Several signals clearly show satellites due to coupling with the tin atom ( 117 Sn and 119 Sn, I ¼ 1/2, natural abundance of 7.61% and 8.58%). The highest value of the 13 A similar analysis of NMR data of products obtained in reaction of Ph 3 SnH and nbd made it possible to detect Ph 3 Sn-nbe as a ca. 50:50 mixture of endo and exo isomers.…”

Carbonyl Complexes of Molybdenum and their Catalytic Activity

“…Carbonyl complexes of molybdenum are of great utility owing to their applications as precursors for the generation of true catalysts for such reactions as metathesis , metathesis polymerization and oligomerization [39][40][41][42][43][44][45][46][47][48][49][50][51][52][53][54][55][56], radical reactions [57][58][59][60][61][62][63][64][65], hydrogenation [66][67][68][69][70][71][72][73][74], hydrosilylation [75][76][77][78][79], hydrogermylation [80,81], hydrostannation [82][83][84][85][86][87]…”

“…In that way the coordinated alkene or alkyne can be transformed to a carbene ligand [8-25, 45, 46, 50]. The activation of a -bond (H H, H C, H Si, H Ge, H Sn) of a substrate such as dihydrogen [66][67][68][69], silane [75][76][77][78], germane [80][81], stannane [82], or aromatic hydrocarbon molecules is a key step in the catalytic transformation of such molecules. Recent investigations of molybdenum carbonyl complexes have revealed novel types of their reactivity toward unsaturated organic compounds, e.g.…”

“…Recent investigations of molybdenum carbonyl complexes have revealed novel types of their reactivity toward unsaturated organic compounds, e.g. in hydrosilylation hydrogermylation and hydrostannation of norbornadiene [78,80,88].…”

Reduction of Aromatic and Aliphatic Esters Using the Reducing Systems MoO2(acac)2 or V(O)(OiPr)3 in Combination with 1,1,3,3‐Tetramethyldisiloxane

“…Since then, other molybdenum complexes have been employed for hydrosilylation. [36,37,38] In our laboratory, TMDS has already been employed to efficiently reduce a range of functions such as phosphane oxides, [39] nitriles, [40] amides, [41] nitro, [42] acetals, [43] and ketones [44] depending on the nature of the metal catalyst. We report herein a new method for the reduction of aromatic or aliphatic esters into alcohols using TMDS as reducing agent in association with two different metal sources to compare their reactivity.…”