The In 2 O 3 /Bi 2 WO 6 heterostructured microbelts with the diameters around 500 nm-1 lm have been fabricated by electrospinning combined with the annealing process. The as-prepared microbelts were characterized by thermogravimetric and differential scanning calorimetry, fourier transform infrared spectroscope, X-ray diffraction, scanning electron microscope and transmission electron microscope. It was found that the In 2 O 3 /Bi 2 WO 6 microbelts reported here showed the well-defined morphology. Additionally, In 2 O 3 /Bi 2 WO 6 heterostructured microbelts exhibit the enhanced photocatalytic activity under the simulated sunlight irradiation compared with the pure Bi 2 WO 6 microbelts.