“…Recent advancements have led to the development of superhydrophobic surfaces that embody both high water repellency and enhanced durability [7,9,[12][13][14]. To achieve robust superhydrophobicity, it involves structuring surfaces at two distinct scales: nanosacle structure for water repellency and microscale structure for durability [15].…”
In this study, a superhydrophobic coating with excellent mechanical durability, chemical stability, anti-icing property and self-cleaning property was developed based on epoxy resin integrated with modified SiO2 nanoparticles (m-SiO2 NPs). The surface morphology and roughness of the coating were finely controlled by changing the content of m-SiO2 NPs, with optimal hydrophobicity and self-cleaning efficiency observed at the m-SiO2 NPs incorporation of 30 wt.%. Benefitting from the three-dimensional stable micro-nano structure on the coating surface, the coating exhibited durable hydrophobicity upon multiple tape-peeling damages and good resistance to both acidic and alkaline corrosive environments. Furthermore, the SiO2-EP coating showed a prominent anti-icing property which could delay the water freezing time from 96 s to 650 s. This coating underscored its potential for applications in environments prone to ice formation.
“…Recent advancements have led to the development of superhydrophobic surfaces that embody both high water repellency and enhanced durability [7,9,[12][13][14]. To achieve robust superhydrophobicity, it involves structuring surfaces at two distinct scales: nanosacle structure for water repellency and microscale structure for durability [15].…”
In this study, a superhydrophobic coating with excellent mechanical durability, chemical stability, anti-icing property and self-cleaning property was developed based on epoxy resin integrated with modified SiO2 nanoparticles (m-SiO2 NPs). The surface morphology and roughness of the coating were finely controlled by changing the content of m-SiO2 NPs, with optimal hydrophobicity and self-cleaning efficiency observed at the m-SiO2 NPs incorporation of 30 wt.%. Benefitting from the three-dimensional stable micro-nano structure on the coating surface, the coating exhibited durable hydrophobicity upon multiple tape-peeling damages and good resistance to both acidic and alkaline corrosive environments. Furthermore, the SiO2-EP coating showed a prominent anti-icing property which could delay the water freezing time from 96 s to 650 s. This coating underscored its potential for applications in environments prone to ice formation.
The homogeneous dispersion of multi‐walled carbon nanotubes (MWCNTs) in a polymer matrix significantly affects the overall properties of composites. In this study, MWCNTs/epoxy (EP) composites were prepared using DeoxyriboNucleic acid (DNA) as a dispersant. The MWCNTs were uniformly dispersed in a phenalkamine curing agent and crosslinked with an epoxy resin matrix. The non‐covalent functionalization of DNA‐dispersed MWCNTs was confirmed by characterizing both the pristine and DNA‐modified MWCNTs. Additionally, the dispersion state and stability of MWCNTs in the curing agent solution were evaluated. Tensile strength and single‐lap‐shear (SLS) were employed to assess the mechanical properties of the composites. The results indicated that the DNA‐dispersed MWCNTs composites exhibited superior strength and toughness, with tensile and shear strengths of 46.81 and 19.64 MPa, respectively, at optimal ratios. These values represent increases of 68.38% and 50.96% compared to pure EP. Dynamic mechanical thermal analysis (DMTA) revealed that the energy storage modulus of DNA‐dispersed MWCNTs/EP composites increased to 2722 MPa, a 24.7% enhancement over pure EP. Furthermore, the thermal properties of the composites were thoroughly investigated. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) showed that the initial decomposition temperature of the DNA‐assisted dispersed composites rose to 330°C. The macromolecular relaxation of the EP materials occurred at higher temperatures, leading to an increased glass transition temperature.Highlights
DNA was used to disperse MWCNTs in phenalkamine curing agent.
MWCNTs/EP composites were made by crosslinking DNA‐dispersed MWCNTs with epoxy resin.
DNA‐dispersed MWCNTs boosted tensile and lap shear strength.
Thermal properties improved due to DNA‐dispersed MWCNTs, and increased the energy storage modulus of the composite.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.