Facile Construction of Three-Dimensional Heterostructured CuCo2S4 Bifunctional Catalyst for Alkaline Water Electrolysis

Abstract

Developing an efficient multi-functional electrocatalyst with high efficiency and low cost to replace noble metals is significantly crucial for the industrial water electrolysis process and for producing sustainable green hydrogen (H2) fuel. Herein, ultrathin CuCo2S4 nanosheets assembled into highly open three-dimensional (3D) nanospheres of CuCo2S4 (Cu/Co = 33:67) were prepared by a facile one-pot solvothermal approach and utilized as a bifunctional electrocatalyst for efficient overall water splitting. The as-prepared CuCo2S4 is characterized structurally and morphologically; the BET surface area of the CuCo2S4 (Cu/Co = 33:67) catalyst was found to have a larger specific surface area (21.783 m2g−1) than that of other catalysts with a Cu/Co ratio of 67:33, 50:50, and 20:80. Benefiting from a highly open structure and ultrathin nanosheets with excellent exposure to catalytically active sites, CuCo2S4 (Cu/Co = 33:67) is identified as an efficient catalyst for the proton reduction and oxygen evolution reactions in 1 M KOH with an overpotential of 182 and 274 mV at 10 mA cm−2, respectively. As expected, a low cell voltage of 1.68 V delivers a current density of 10 mA cm−2. Stability and durability are also greatly enhanced under harsh alkaline conditions. Therefore, this work provides a simple strategy for the rational design of spinel-based transition metal sulfide catalysts for electrocatalysis.

Hydrothermal Prepared Bramble-like Double Arrays NiCo2S4 Bifunctional Electrocatalysts for High-Efficiency Water Splitting

“…The optimized energy level alignment caused by Co and introduced more active sites caused by its unique 3D bramble-like structure imported better structural stability with higher electronic transfer abilities and showed higher electrochemical activity. Importantly, the performance of NiCo 2 S 4 /NF catalyst was superior to some recently reported bifunctional electrocatalysts as shown in Figure d − and furthermore certified that the NiCo 2 S 4 /NF catalyst had an excellent electroceutical ability.…”

Oxygen Vacancy-Enriched Amorphous Transition Metal Ternary Oxides toward Highly Efficient Oxygen Evolution Reaction

“…As shown Figure S5a, the adsorption−desorption curve of FeNiCoO x /CoO x /CP is a type-IV isotherm with a hysteresis loop at 0.4 of P/P 0 , indicating its mesoporous structure. 42 The pore size distribution determined by the Barrett−Joyner−Halenda (BJH) model exhibits the mesopore feature of the as-synthesized FeNiCoO x /CoO x ranging from 2 to 50 nm (Figure S5b), effectively promoting the mass transport. 43,44 The Brunauer−Emmett−Teller (BET) surface area of FeNiCoO x /CoO x is 13.868 m 2 g −1 , much higher than that of CoO x /CP (5.323 m 2 g −1 ) (Figure S5c and S5d), suggesting more exposed active sites after the deposition of FeNiCoO x .…”