“…Therefore, recently, some non‐conventional techniques in combination with conventional photolithography have been proposed for the preparation of nanoelectrodes, nanogaps and other nano‐scaled devices. These techniques include, for instance, a photoresist thermal reflow and shrinking (Meng et al , 2001) or photoresist ashing technique (Kim et al , 2008), a shadow evaporation process (Ishida et al , 2005), a controlled size‐reduction using the oxidation of Si (Choi et al , 2003; Hashioka et al , 2005; Cho et al , 2007) or laser‐assisted electrochemical etching (Juhasz and Linnros, 2002), chemical‐mechanical polishing (Lee et al , 2003), the decrease of separation between metallic electrodes by means of an electro‐deposition from an electrolyte solution (Morpurgo et al , 1999), methods that utilize a sidewall structure (Chung et al , 2002), a self‐aligned plasma etching of a silicon dioxide layer and silicon substrate (Georgiev et al , 2003), or a lateral, partial anodic oxidation of the side‐edge of a photolithographically‐structured metallic film (e.g. Ti) (Hashioka et al , 2003), techniques that use a silicon‐on‐insulator structure (Strobel et al , 2007), etc.…”